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Preface -- Part I Introduction and Concepts -- 1 Anatomy of a Redox-Active Ligand 3 Marine Desage-El Murr -- 1.1 Introduction -- 1.2 Biological Inspiration: From the Enzyme to the Flask, a Continued Journey -- 1.3 Chemical History: Puzzle-Solving for Coordination Chemists -- 1.4 Combining Spectroscopy and Theory: How to Spot a Redox-Active Ligand? -- 1.5 Non-innocent, Cooperative, Electro-Active, or Redox-Active? -- 1.6 Unusual Ligands and Unusual Reactivities with a Redox-Active Ligand -- 1.7 Perspectives and Concluding Remarks -- 2 Mechanistic Studies of Catalytic Nitrene-Transfer Reactions Involving Redox-Active Ligands and Substrates 21 Nicolaas P. van Leest, Jarl Ivar van der Vlugt, and Bas de Bruin -- 2.1 Introduction -- 2.2 Characterization of Radical-type Intermediates -- 2.3 Mechanistic Studies -- 2.4 Case Studies for Nitrene Transfer Aided by Redox-Active Ligands and Substrates -- 3 Redox-Active Ligands From a Computational Perspective 53 Roy Eckhardt, Dorys Reyes, Christian Sandoval-Pauker, and Balazs Pinter -- 3.1 Introduction -- 3.2 Electronic Structure Determination Through DFT and Spectroscopy -- 3.3 Redox-Active Ligands as Electron Reservoirs -- 3.4 In Silico Description and Engineering of Redox-Active Ligands -- 3.5 Conclusions -- Part II Applications -- 4 Complexes of Stable N-aryl Radicals and Their Catalytic Applications 109 Nicolas Leconte and Fabrice Thomas -- 4.1 Introduction and General Considerations on Exocyclic N-aryl Radicals -- 4.2 Complexes Featuring Anilinyl Radicals -- 4.3 Bidentate o-diaminobenzenes and Their Radicals -- 4.4 Pincer Ligands and Their Radicals -- 4.5 Branched Tetradentate o-diaminobenzene and Associated Radicals -- 4.6 Polydentate Ligands Featuring One Bidentate Diiminosemiquinone Radical -- 4.7 Representative Catalytic Applications -- 4.8 Conclusion -- 5 Redox-Active Ligands in Coordination Chemistry and Organic Synthesis 151 Toru Amaya, Toshiyuki Moriuchi, and Toshikazu Hirao -- 5.1 Introduction -- 5.2 Controlled Formation of Conjugated Complexes with Redox-Active Polyanilines or 1,4-Benzoquinonediimines -- 5.3 Catalytic Application of Hybrid Systems Consisting of Redox-Active Polyanilines and Transition Metals -- 5.4 Conclusion -- 6 Metal Complexes Bearing Redox-Active Supporting Ligands that Promote Chemical Transformations Involving Protons and Electrons 175 Kundan K. Singh and Isaac Garcia-Bosch -- 6.1 Introduction -- 6.2 Dioxygen Reduction toWater -- 6.3 Dioxygen Reduction Coupled with Substrate Dehydrogenation -- 6.4 Dioxygen Reduction Coupled with Substrate Hydroxylation -- 6.5 Conclusions and Future Perspectives -- Part III Case Studies -- 7 Redox-Active Guanidine Ligands 199 Hans-Jörg Himmel -- 7.1 Introduction -- 7.2 Properties and Reactivity of Uncoordinated Redox-Active Guanidines -- 7.3 Redox-Active Guanidines as Ligands in Coordination Chemistry -- 7.4 Perspectives -- 8 Coordination Chemistry with Lanthanides and Redox-Active Ligands 249 Valeriu Cemortan and Grégory Nocton -- 8.1 Introduction -- 8.2 Quinone, Iminoquinone, and O-phenylenediamine-Based Complexes -- 8.3 Diazadienes -- 8.4 Iminopyridines and Bis(imino)pyridines -- 8.5 Nitroxides -- 8.6 N-heterocycles -- 8.7 Conclusion and Outlook -- 9 Actinide Complexes of Redox Non-innocent Ligands 317 Karlotta van Rees and Jason B. Love -- 9.1 Bipyridyl Ligands -- 9.2 Pyrrole Ligands -- 9.3 Tmtaa Ligand -- 9.4 Schiff-Base Ligands -- 9.5 Pyridine(di-imine) Ligands -- 9.6 Phosphite Ligands -- 9.7 Quinone Ligands -- 9.8 Aryloxide Ligands -- 9.9 Conclusion -- References -- Index.

Redox-Active Ligands Authoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesis, the characterization of their coordination complexes, and important applications in homogeneous catalysis. The work reflects the diversity of the subject by including ongoing research spanning coordination chemistry, organometallic chemistry, bioinspired catalysis, proton and electron transfer, and the ability of such ligands to interact with early and late transition metals, lanthanides, and actinides. The book is divided into three parts, devoted to introduction and concepts, applications, and case studies. After the introduction on key concepts related to the field, and the different types of ligands and complexes in which ligand-centered redox activity is commonly observed, mechanistic and computational studies are described. The second part focuses on catalytic applications of redox-active complexes, including examples from radical transformations, coordination chemistry and organic synthesis. Finally, case studies of redox-active guanidine ligands, and of lanthanides and actinides are presented. Other specific sample topics covered include: An overview of the electronic features of redox-active ligands, covering their historical perspective and biological background The versatility and mode of action of redox-active ligands, which sets them apart from more classic and tunable ligands such as phosphines or N-heterocyclic carbenes Preparation and catalytic applications of complexes of stable N-aryl radicals Metal complexes with redox-active ligands in H+/e- transfer transformations By providing up-to-date information on important concepts and applications, Redox-Active Ligands is an essential reading for researchers working in organometallic and coordination chemistry, catalysis, organic synthesis, and (bio)inorganic chemistry, as well as newcomers to the field.

Library	Material Type	Item Barcode	Shelf Number	[[missing key: search.ChildField.HOLDING]]	Status
Online Library	E-Book	598911-1001	QD474		Wiley E-Kitap Koleksiyonu