Alkane functionalization

Title:

Author:

Pombeiro, A. J. L. (Armando J. L.), editor.

ISBN:

9781119379232

9781119379249

9781119379256

Physical Description:

1 online resource

Contents:

Alkane Functionalization: Introduction and Overview / Armando J L Pombeiro -- C-O Bond Formation. Hydroxylation and Other Oxygenation Reactions -- Activation and Oxidative Functionalization of Alkanes with Noble-Metal Catalysts: Molecular Mechanisms / Evgeniy G Chepaikin -- Alkane-Oxidizing Systems Based on Metal Complexes. Radical Versus Nonradical Mechanisms / Georgiy B Shul'pin -- Reactions of Alkyl Radicals in Aqueous Solutions / Dan Meyerstein -- C-H Bond Oxidation with Transition-Metal-Based Carbene Complexes / Bruno Dominelli, Anja C Lindhorst, Fritz E Kühn -- Alkane Oxidation with C-Scorpionate Metal Complexes / Luísa M D R S Martins -- Alkane Oxidation with Multinuclear Heterometallic Catalysts / Dmytro S Nesterov, Oksana V Nesterova, Armando J L Pombeiro -- Oxidative Functionalization of Methane on Heterogeneous Catalysts / Maricruz Sanchez-Sanchez, Johannes A Lercher -- Gas-Phase Oxidation of Alkanes / Fabrizio Cavani, Alessandro Chieregato, Jose M López Nieto, Jean-Marc M Millet -- Bioinspired Alkane Functionalization -- Recent Developments of Bioinspired Approaches to Functionalization of Light Alkanes / Alexander B Sorokin -- Regioselectivity of Non-heme Iron Catalysts for C-H Activation / Christian R Goldsmith -- Imine-based Iron and Manganese Complexes as Catalysts for Alkane Functionalization / Giorgio Olivo, Osvaldo Lanzalunga, Stefano Di Stefano -- Alkane Oxidation with Biologically Inspired Nonheme Iron Catalysts Based in the Triazacyclononane Ligand Scaffold / Miquel Costas -- The Nature of High-Valent Oxometal Intermediates of Iron-Aminopyridine Mediated Oxidations / Oleg Y Lyakin, Konstantin P Bryliakov, Evgenii P Talsi -- Selective Oxidation of Alkanes by Metallo-Monooxygenases and Their Nanobiomimetics / Chih-Cheng Liu, Yi-Fang Tsai, Wondemagegn H Wanna, Ravirala Ramu, Damodar Janmanchi, Sunney I Chan, Steve S-F Yu -- Alkane Oxidation with Vanadium and Copper Catalysts / Manas Sutradhar, Luísa M D R S Martins, M Fátima C Guedes da Silva, Armando J L Pombeiro -- C-B, C-C and C-N Bond Formation -- Catalytic Borylation of Methane: Combining Computational and High-Throughput Screening Approaches to Discover a New Catalyst / Pavel Zatsepin, Dieter Sorsche, Seihwan Ahn, Mu-Hyun Baik, Daniel J Mindiola -- Alkane Carbonylation and Carbene Insertion Reactions / Ana M Faisca Phillips, Armando J L Pombeiro -- Catalytic Alkane Amidation and Related Reactions / Dmytro S Nesterov, Luís M T Frija, Armando J L Pombeiro, Maximilian N Kopylovich -- Dehydrogenation Reactions -- Oxidative and Nonoxidative Routes to Alkane Dehydrogenation / Jay A Labinger -- Dehydrogenation of Alkanes Using Molecular Catalysts / Huaquan Fang, Guixia Liu, Zheng Huang -- Unconventional Systems -- Nontransition Metal Catalyzed Oxidation of Alkanes with Peroxides / Maxim L Kuznetsov -- Metal-Free Functionalization of Alkanes / Jincan Zhao, Jianlin Han -- Alkane Functionalization under Unconventional Conditions: in Ionic Liquid, in Supercritical CO2, and Microwave Assisted / Ana P C Ribeiro, Elisabete C B A Alegria, António Palavra, Armando J L Pombeiro -- Noncovalent Interactions in Alkane Chemistry / Kamran T Mahmudov, M Fátima C Guedes da Silva, Fedor I Zubkov, Armando J L Pombeiro -- Alkane Complexation / Robert H Crabtree -- Alkane-Related C-H Bond Activation and Functionalization of Aliphatic Amines / Christian Bruneau, Mathieu Achard.

Abstract:

Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.

Local Note:

John Wiley and Sons

Subject Term:

Alkanes.

Organic compounds -- Synthesis.

Alcanes.

Composés organiques -- Synthèse.

alkane.

SCIENCE -- Chemistry -- Organic.

Organic.

Chemistry.

SCIENCE.