Experimental and theoretical approaches to actinide chemistry

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Title:

Author:

Gibson, John K. (John Knight), editor.

ISBN:

9781119115533

9781119115557

Physical Description:

1 online resource

Contents:

1.1.Introduction / Kirk A. Peterson / Michael C. Heaven -- 1.2.Techniques for Obtaining Actinide-Containing Molecules in the Gas Phase / Kirk A. Peterson / Michael C. Heaven -- 1.3.Techniques for Spectroscopic Characterization of Gas-Phase Actinide Compounds / Kirk A. Peterson / Michael C. Heaven -- 1.3.1.Conventional Absorption and Emission Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.3.2.Photoelectron Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.3.3.Velocity Modulation and Frequency Comb Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.3.4.LIF Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.3.5.Two-Photon Excitation Techniques / Kirk A. Peterson / Michael C. Heaven -- 1.3.6.Anion Photodetachment Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.3.7.Action Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.3.8.Bond Energies and Reactivities from Mass Spectrometry / Kirk A. Peterson / Michael C. Heaven -- 1.4.Considerations for Characterizing Actinide-Containing Molecules in the Gas Phase by Ab Initio Methods / Kirk A. Peterson / Michael C. Heaven -- 1.4.1.Electron Correlation Methods / Kirk A. Peterson / Michael C. Heaven -- 1.4.2.Relativistic Effects / Kirk A. Peterson / Michael C. Heaven -- 1.4.3.Basis Sets / Kirk A. Peterson / Michael C. Heaven -- 1.5.Computational Strategies for Accurate Thermodynamics of Gas-Phase Actinide Molecules / Kirk A. Peterson / Michael C. Heaven -- 1.6.Ab Initio Molecular Spectroscopy of Gas-Phase Actinide Compounds / Kirk A. Peterson / Michael C. Heaven -- 1.6.1.Pure Rotational and Ro-Vibrational Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.6.2.Electronic Spectroscopy / Kirk A. Peterson / Michael C. Heaven -- 1.7.Summary and Outlook / Kirk A. Peterson / Michael C. Heaven -- Acknowledgments / Kirk A. Peterson / Michael C. Heaven -- References / Kirk A. Peterson / Michael C. Heaven -- 2.1.Introduction / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.2.Potentiometry / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.2.1.Potentiometric Titrations to Reveal Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.2.2.Overview of Potentiometry in Aqueous Actinide Chemistry / Jennifer N. Wacker / Rami J. Batrice / Karah E. Knope -- 2.3.Optical Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.3.1.UV-vis-NIR Spectroscopy in Actinide Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.3.2.Fluorescence Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.3.3.Overview of Optical Spectroscopy in Aqueous Actinide Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.4.NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.4.1.Probing Chemical Equilibria by NMR / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.4.2.Monitoring Product Formation/Evolution by NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.4.3.Monitoring Actinide Self-Assembly by NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.4.4.Following Cluster Stability in Solution by NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.4.5.Overview of NMR Spectroscopy in Aqueous Actinide Chemistry / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.Raman Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.1.Cluster Formation and Assembly / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.2.Spectral Deconvolution of Raman Data to Yield Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.3.Identifying the Nature of Cation-Cation Interactions in Solution / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.4.In the Absence of an "y1": Pa(V) Speciation in HF Solutions / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.5.Computational Assignment of Vibrational Spectra / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.5.6.Overview of Raman Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.6.X-ray Absorption Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.6.1.EXAFS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.6.2.Actinide Solution Speciation by EXAFS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.6.3.EXAFS Structural Comparison of Complexes with Varying Oxidation States and Geometries / Karah E. Knope / Jennifer N. Wacker / Rami J. Batrice -- 2.6.4.Overview of EXAFS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.7.Small-Angle X-ray Scattering (SAXS) / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.7.1.Structure Elucidation by SAXS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.7.2.SAXS Analysis of Cluster Evolution / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.7.3.Understanding Self-Assembly Processes by SAXS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.7.4.Overview of SAXS / Rami J. Batrice / Jennifer N. Wacker / Karah E. Knope -- 2.8.High-Energy X-ray Scattering (HEXS) / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.8.1.Determining Coordination Number and Environment about a Metal Center / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.8.2.Deducing Metal-Ligand Coordination Modes / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.8.3.Following Oligomer Formation and Stability / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 2.8.4.Overview of HEXS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- References / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker -- 3.1.Introduction / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.2.Fluorides / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.2.1.Trivalent and Tetravalent Fluorides / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.2.2.Pentavalent and Hexavalent Fluorides / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.2.3.Fluoride Architectures / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.3.Borates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.3.1.Functionalized Borates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.3.2.Transuranic Borates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.4.Sulfates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.4.1.Thorium and Uranium / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.4.2.Transuranic Frameworks / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.5.Phosphates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- 3.6.Conclusion / Thomas E. Albrecht-Schmitt / Matthew L. Marsh -- References / Matthew L. Marsh / Thomas E. Albrecht-Schmitt -- 4.1.Introduction / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.2.Overview of Actinide Organometallic Chemistry / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.2.1.Overview of Thorium Organometallics / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.2.2.Overview of Uranium Organometallics / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.2.3.Overview of Transuranium Organometallics / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.3.Overview of Theoretical Methods / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.4.New Theoretical and Experimental Tools for Evaluating Covalency in the 5f Series / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.4.1.The Quantum Theory of Atoms-in-Molecules / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.4.2.Ligand K-edge X-ray Absorption Spectroscopy / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.4.3.Optical Spectroscopy / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.4.4.Nuclear Magnetic Resonance (NMR) Spectroscopy / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.4.5.Electrochemistry / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.5.Notable Discoveries in Actinide-Carbon Chemistry / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.5.1.An(II) Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.5.2.Pi-Acceptor Ligand Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.5.3.(Inverted) Arene Sandwich Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.5.4.Phosphorano-Stabilized Carbene Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.5.5.Homoleptic Alkyl and Aryl Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.6.Single and Multiple Bonding between Uranium and Group 15 Elements / Nikolas Kaltsoyannis / Trevor W.

Hayton -- 4.7.Complexes with Group 16 Donor Ligands / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.7.1.Terminal Mono-oxo Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.7.2.Complexes with Heavy Chalcogen (S, Se, Te) Donors / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.8.ACtinyl and Its Derivatives / Trevor W. Hayton / Nikolas Kaltsoyannis -- 4.8.1.Inverse Trans Influence (ITI) / Trevor W. Hayton / Nikolas Kaltsoyannis -- 4.8.2.Imido-Substituted Analogues of Uranyl / Trevor W. Hayton / Nikolas Kaltsoyannis -- 4.8.3.Progress Toward the Isolation of a cis-Uranyl Complex / Nikolas Kaltsoyannis / Trevor W. Hayton -- 4.9.Organoactinide Single-Molecule Magnets / Trevor W. Hayton / Nikolas Kaltsoyannis -- 4.10.Future Work / Nikolas Kaltsoyannis / Trevor W. Hayton -- Acknowledgments / Trevor W. Hayton / Nikolas Kaltsoyannis -- References / Trevor W. Hayton / Nikolas Kaltsoyannis -- 5.1.Introduction / Aurora E. Clark / Ping Yang / Jenifer C. Shafer -- 5.2.Overview of Separations Processes / Aurora E. Clark / Ping Yang / Jenifer C. Shafer -- 5.2.1.Classic Processes-U/Pu Recovery / Ping Yang / Aurora E. Clark / Jenifer C. Shafer -- 5.2.2.Advanced Separation Processes-Am/Cm Recovery / Aurora E. Clark / Ping Yang / Jenifer C. Shafer -- 5.2.3.Aqueous-Based Complexants for Trivalent An/Ln Separation / Ping Yang / Aurora E. Clark / Jenifer C. Shafer -- 5.2.4.Recent Trends in Aqueous-Based Trivalent An/Ln Separations / Aurora E. Clark / Ping Yang / Jenifer C. Shafer

Abstract:

A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts in the field, the text includes information on new advances in experiment and theory and reveals the interplay between these two realms. The authors offer a multidisciplinary and multimodal approach to the nature of actinide chemistry, and explore the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry. The text covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques. The authors provide contemporary overviews of each topic area presented and describe the current and anticipated experimental approaches for the field, as well as the current and future computational chemistry and materials techniques. In addition, the authors explore the combination of experiment and theory. This important resource: -Provides an essential resource the reviews the key aspects of contemporary actinide research -Includes information on new advances in experiment and theory, and the interplay between the two -Covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques -Focuses on the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry Written for academics, students, professionals and researchers, this vital text contains a thorough review of the key aspects of actinide research and explores the most recent advances in experiment and theory.

Local Note:

John Wiley and Sons

Subject Term:

Actinium compounds.

Actinide elements.

Heavy elements.

Actinoid Series Elements

Actinides.

Éléments lourds.

SCIENCE -- Chemistry -- Inorganic.

Inorganic.

Chemistry.