Cover image for Organosilicon chemistry : novel approaches and reactions
Title:
Organosilicon chemistry : novel approaches and reactions
Author:
Hiyama, Tamejiro, 1946- editor.
ISBN:
9783527814787

9783527814756
Physical Description:
1 online resource
Contents:
Catalytic generation of silicon nucleophiles / Si-H bond activation by main-group Lewis acids / SiH bond activation by transition-metal Lewis acids / Metal-ligand cooperative Si-H bond activation / Cationic silicon-based Lewis acids in catalysis / Transition-metal-catalyzed C-H bond silylation / Transition-metal-free catalytic C-H bond silylation / Silyl-Heck, Silyl-Negishi, and related reactions / Transition-metal-catalyzed cross-coupling of organosilicon compounds / Lewis base activation of silicon Lewis acids / Hydrosilylation catalyzed by base metals / Silylenes as ligands in catalysis / Enantioselective synthesis of silyl ethers through catalytic Si-O bond formation / Chiral silicon molecules
Abstract:
"Provides a unique summary of important catalytic reactions in the presence of silicon. A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules." -- Provided by publisher.
Local Note:
John Wiley and Sons
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