Early Main Group Metal Catalysis : Concepts and Reactions

Title:

Author:

Harder, Sjoerd.

ISBN:

9783527818020

9783527818013

Publication Information:

Newark : John Wiley & Sons, Incorporated, 2020.

Physical Description:

1 online resource (402 pages)

General Note:

Includes index.

Contents:

Introduction to Early Main Group Organometallic Chemistry and Catalysis / Sjoerd Harder -- Polymerization of Alkenes and Polar Monomers by Early Main Group Metal Complexes / Sjoerd Harder -- Intramolecular Hydroamination of Alkenes / Sebastian Bestgen, Peter W Roesky -- Molecular s-Block Catalysts for Alkene Hydrophosphination and Related Reactions / Yann Sarazin, Jean-François Carpentier -- H-N and H-P Bond Addition to Alkynes and Heterocumulenes / Sven Krieck, Matthias Westerhausen -- Early Main Group Metal-Catalyzed Hydrosilylation of Unsaturated Bonds / Sjoerd Harder -- Early Main Group Metal Catalyzed Hydrogenation / Heiko Bauer, Sjoerd Harder -- Alkali and Alkaline Earth Element-Catalyzed Hydroboration Reactions / Aaron D Sadow -- Dehydrocoupling and Other Cross-couplings / Merle Arrowsmith -- Enantioselective Catalysis with s-Block Organometallics / Philipp Stegner, Sjoerd Harder -- Early Main Group Metal Lewis Acid Catalysis / Marian Rauser, Sebastian Schröder, Meike Niggemann -- Enantioselective Group 2 Metal Lewis Acid Catalysis / Yasuhiro Yamashita, Tetsu Tsubogo, Shū Kobayashi -- Miscellaneous Reactions / Michael S Hill.

Abstract:

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Local Note:

John Wiley and Sons

Subject Term:

Metal catalysts.

Catalysis.

Catalyseurs métalliques.

Catalyse.

Materials Science.

TECHNOLOGY & ENGINEERING.

Catalysis

Metal catalysts

Genre: