Organic Reaction Mechanisms 2016 : an Annual Survey Covering the Literature Dated January to December 2016

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Title:

Author:

Knipe, A. C.

ISBN:

9781119288657

9781119288732

Publication Information:

Newark : Wiley, 2020.

Physical Description:

1 online resource (870 pages)

Series:

Organic Reaction Mechanisms Ser.

Contents:

Cover -- Title Page -- Copyright -- Contributors -- Preface -- Contents -- Chapter 1 Reactions of Aldehydes and Ketones and Their Derivatives -- Formation and Reactions of Acetals and Related Species -- Reactions of Glucosides -- Reactions of Ketenes and Related Cumulenes -- Formation and Reactions of Nitrogen Derivatives -- C-C Bond Formation and Fission: Aldol and Related Reactions -- Other Addition Reactions -- Enolization, Reactions of Enolates, and Related Reactions -- Oxidation and Reduction of Carbonyl Compounds -- Miscellaneous Cyclizations -- Other Reactions -- References

Chapter 2 Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives -- Intermolecular Catalysis and Reactions -- Carboxylic Acids and their Derivatives -- Phosphoric Acids and their Derivatives -- Intramolecular Catalysis and Neighbouring Group Participation -- Biologically Significant Reactions -- Carboxylic Acids and their Derivatives -- Phosphoric Acids and their Derivatives -- References -- Chapter 3 Oxidation and Reduction -- Oxidation by Metal Ions and Related Species -- Oxidation by Compounds of Non-metallic Elements -- Ozonolysis and Ozonation -- Peracids and Peroxides

Photo-oxygenation and Singlet Oxygen -- Triplet Oxygen and Autoxidation -- Other Oxidations -- Reduction by Complex Metal Hydrides -- Hydrogenation -- Transfer Hydrogenation -- Other Reductions -- References -- Chapter 4 Carbenes and Nitrenes -- Reviews -- Metal-Free Carbenes -- Structure and Reactivity -- Metallated Carbenes -- Structure and Reactivity -- Heterocyclic Carbenes -- Structure -- Heterocyclic Carbenes -- Reactivity -- Heterocyclic Carbenes -- DFT Analysis Methods -- Heterocyclic Carbenes -- As Ligands -- N-Heterocyclic Carbenes -- Chiral Systems -- Nitrenes -- Silylenes and Germylenes

Propargyl and Vinyl Carbocations -- Asymmetric Synthesis -- Biosynthetic Chemistry -- References -- Chapter 7 Nucleophilic Aliphatic Substitution -- SN Reactions Forming C-C Bonds -- Allylic Substitutions -- Vinyl Substitutions -- Propargylic Substitutions -- Reactions of Cyclic Ethers -- Aziridines and Other Small Ring Substitution Reactions -- Studies Using Kinetic Isotope Effects -- Nucleophilic Substitution on Elements Other than Carbon -- Medium Effects/Solvent Effects -- Structural Effects -- Theoretical Studies -- Miscellaneous Kinetic and Product Studies -- Other -- Acknowledgement

Abstract:

Organic Reaction Mechanisms 2016, the 52nd annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2016. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements.

Local Note:

John Wiley and Sons

Subject Term:

Organic reaction mechanisms.

Réactions organiques (Chimie) -- Mécanismes.

Organic.

Chemistry.

SCIENCE.

Organic reaction mechanisms

Genre:

Electronic books.

Added Author: