3.2.2 Synthesis of Esters and Functionalizations of Nitriles and Alkanes -- 3.2.3 Synthesis and Derivatization of Heterocycles -- 3.3 Hydrogen-Borrowing Reactions -- 3.3.1 Alkylation of Amines -- 3.3.2 Alkylation of Alcohols and Ketones -- 3.3.3 Alkylation of Amides and Esters -- 3.3.4 Alkylation of Nitriles and Sulfonamide -- 3.3.5 Upgrading of Ethanol into 1-Butanol -- 3.3.6 Alkylation of Hydrazine -- 3.3.7 Combining Acceptorless Dehydrogenative Coupling with Hydrogen-Borrowing -- 3.4 Conclusions and Perspectives -- References -- Chapter 4 Manganese-Catalyzed Hydrosilylation and Hydroboration Reactions -- 4.1 Introduction -- 4.2 Hydrosilylation -- 4.2.1 Hydrosilylation of Carbonyls and Carboxylates -- 4.2.2 Hydrosilylation of Amides -- 4.2.3 Hydrosilylation of Carbon Dioxide -- 4.2.4 Hydrosilylation of C C and C C Bonds -- 4.2.4.1 Olefin Hydrosilylation -- 4.2.4.2 Alkyne Hydrosilylation -- 4.3 Hydroboration -- 4.3.1 Hydroboration of C O Bonds -- 4.3.2 Hydroboration of Alkenes -- 4.3.3 Hydroboration of Alkynes -- 4.3.4 Hydroboration of Nitriles -- 4.4 Summary and Conclusions -- References -- Chapter 5 Manganese Complexes for Electro- and Photocatalytic Transformations -- 5.1 Introduction -- 5.2 Mn-Catalyzed Organic Oxidations -- 5.3 Mn-Catalyzed Reductions and Other Organic Transformations -- 5.4 Mn-Catalyzed CO2 Reduction -- 5.4.1 Electrocatalytic CO2 Reduction with Manganese-Based Catalysts -- 5.4.1.1 Pyridine-Based Complexes -- 5.4.1.2 Diimine-Based Complexes -- 5.4.1.3 N-Heterocyclic Carbene-Based Complexes -- 5.4.2 Photochemical CO2 Reduction -- 5.4.3 Heterogenization of Molecular Mn Catalysts for the CO2 Reduction Reaction -- 5.5 Conclusions -- References -- Chapter 6 Manganese-Catalyzed C H Oxygenation Reactions -- 6.1 Introduction -- 6.2 Selective Manganese-Catalyzed C-H Oxidation Reactions: Early Studies.

6.3 Manganese-Catalyzed Chemo- and Regioselective C-H Oxidations with Hydrogen Peroxide -- 6.4 Manganese-Catalyzed Enantioselective C-H Oxidations -- 6.5 Manganese-Catalyzed Oxidative Desymmetrizations -- 6.6 Mn-Catalyzed Oxidative Kinetic Resolution of sec-Alcohols -- 6.7 Mn-Catalyzed Oxidation of Aromatic Compounds -- 6.8 Summary and Conclusions -- Acknowledgment -- References -- Chapter 7 Manganese-Catalyzed Organometallic C H Activation -- 7.1 Introduction -- 7.2 Stoichiometric Cyclometalation with Manganese Complexes -- 7.3 Manganese-Catalyzed C C Bond Formation via Directed C H Activation -- 7.3.1 Insertion of C C Bonds into Manganacycles -- 7.3.2 Insertion of C C Bonds into Manganacycles -- 7.3.3 Insertion of Allene into Manganacycles -- 7.3.4 Insertion of C X (X & -- equals -- O, N) Bond into Manganacycles -- 7.3.5 Miscellaneous Reactions Involving C-H Activation -- 7.4 Summary and Outlook -- References -- Chapter 8 Manganese-Catalyzed Cross-Coupling Processes -- 8.1 Introduction -- 8.2 C C Bond Formation via Mn-Catalyzed Cross-Coupling Reactions -- 8.2.1 Mn-Catalyzed Kumada Cross-Coupling Reactions -- 8.2.1.1 Aryl Halides with Grignard Reagents -- 8.2.1.2 Heteroaryl Halides with Grignard Reagents -- 8.2.1.3 Vinyl(Pseudo)Halides with Grignard Reagents -- 8.2.1.4 Conclusion on Mn-Catalyzed Kumada Cross-Coupling Reactions -- 8.2.2 Mn-Catalyzed Stille Cross-Coupling Reactions -- 8.2.3 Mn-Catalyzed Coupling Reactions of Organometallic Reagents Under Oxidative Conditions -- 8.2.3.1 Homocoupling Reactions -- 8.2.3.2 Heterocoupling Reactions -- 8.2.4 Mechanistic Insights -- 8.2.5 Conclusion on Mn-Catalyzed Coupling Reactions of Organometallic Reagents Under Oxidative Conditions -- 8.3 Mn-Catalyzed Carbon-Heteroatom Bond Formation -- 8.3.1 C N Bond Formation -- 8.3.2 C O Bond Formation -- 8.3.3 C S Bond Formation -- 8.3.4 C B Bond Formation.

Organometallic Manganese Compounds in Organic Synthesis / Alina A Grineva, Noël Lugan, Dmitry A Valyaev -- Manganese-Catalyzed Hydrogenation and Hydrogen Transfer Reactions / Jean-Baptiste Sortais, Ruqaya Buhaibeh, Yves Canac -- Manganese-Catalyzed Hydrogen-Borrowing and Dehydrogenative Coupling Reactions / Stefan Weber, Karl Kirchner -- Manganese-Catalyzed Hydrosilylation and Hydroboration Reactions / Thao T Nguyen, Ryan J Trovitch -- Manganese Complexes for Electro- and Photocatalytic Transformations / Sergio Fernandez, Geyla C Dubed Bandomo, Julio Lloret-Fillol -- Manganese-Catalyzed C#xF8FF;H Oxygenation Reactions / Konstantin P Bryliakov -- Manganese-Catalyzed Organometallic C #xF8FF; H Activation / Yunhui Yang, Congyang Wang -- Manganese-Catalyzed Cross-Coupling Processes / Xiaoping Liu, Florian Jaroschik, Marc Taillefer -- Manganese( III) Acetate-Mediated Cyclizations / Barry B Snider -- Manganese-Catalyzed Dihydroxylation and Epoxidation of Olefins / Niek NHM Eisink,, Wesley R Browne.