Title:
Organic reaction mechanisms 2020 : an annual survey covering the literature dated January to December 2020
Author:
Moloney, Mark G., editor.
ISBN:
9781119716846
9781119716853
Physical Description:
1 online resource (623 p.)
General Note:
Benzyl, Benzhydryl, and Trityl Cations
Contents:
Cover -- Title Page -- Copyright -- List of Contributors -- Preface -- Contents -- Chapter 1 Reactions of Aldehydes and Ketones and Their Derivatives -- Formation and Reactions of Acetals and Related Species -- Reactions of Glucosides -- Reactions of Ketenes and Related Cumulenes -- Formation and Reactions of Nitrogen Derivatives -- Imines: Synthesis and General and Iminium Chemistry -- Mannich and Mannich-Type Reactions -- Stereoselective Hydrogenation of Imines, and Other Redox Processes -- Cyclizations of Imines -- Other Reactions of Imines -- Oximes, Oxime Ethers, and Oxime Esters
Hydrazones and Related Species -- Iminium Ion Chemistry -- C C Bond Formation and Fission: Aldol and Related Reactions -- The Asymmetric Aldol -- The Morita-Baylis-Hilman Reaction and Its Aza-Variants -- Other Aldol and Aldol-Type Reactions -- The Michael Addition -- The Wittig and Other Olefinations -- Miscellaneous Additions -- Reactions of Enolates and Related Reactions -- Oxidation of Carbonyl Compounds -- Reduction of Carbonyl Compounds -- Miscellaneous Reactions -- References -- Chapter 2 Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and Their Derivatives
Intermolecular Catalysis and Reactions -- Carboxylic Acids and their Derivatives -- Phosphoric Acids and their Derivatives -- Sulfonic Acids and their Derivatives -- Intramolecular Catalysis and Neighboring Group Participation -- Biologically Significant Reactions -- Carboxylic Acids and their Derivatives -- References -- Chapter 3 Oxidation and Reduction -- Oxidation by Metal Ions and Related Species -- Chromium, Manganese, Nickel, and Cobalt -- Copper, Silver, and Gold -- Rhenium, Bismuth, and Tungsten -- Palladium, Iridium, Rhodium, and Platinum -- Group VIII Metals -- Cerium
Oxidation by Compounds of Nonmetallic Elements -- Nitrogen, Sulfur, and Selenium -- Halogens -- Ozonolysis and Ozonation -- Peracids and Peroxides -- Photochemical Oxidation and Singlet Oxygen -- Triplet Oxygen and Autoxidation -- Electrochemical Oxidations -- Other Oxidations -- Reduction by Metal Hydrides -- Hydrogenation -- Transfer Hydrogenation -- Other Reductions -- References -- Chapter 4a Nucleophilic Aromatic Substitution -- General -- Reactions of Arenediazonium Salts -- The SNAr Mechanism -- Meisenheimer and Related Complexes -- Benzyne and Related Intermediates
Transition Metal-Catalyzed Carbon-Carbon Bond Formation -- References -- Chapter 4b Electrophilic Aromatic Substitution -- General Introduction -- Computational Studies -- Protonation and Deuteration -- Halogenation -- Chlorination -- Bromination -- Nitration -- Amidation, Amination, and Azidation -- Oxylation -- Sulfanylation and Sulfonation -- Metallation -- C C Bond-Forming Reactions -- Friedel-Crafts Alkylation -- Friedel-Crafts Acylation -- Arylation -- Miscellaneous FGIs -- References -- Chapter 5 Carbocations -- General -- Vinyl, Allyl, and Propargyl Cations
Abstract:
Organic Reaction Mechanisms 2020 , the 56th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2020. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements Transition Metal Coupling Radicals An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.
Local Note:
John Wiley and Sons
Genre:
Added Author:
Electronic Access:
https://onlinelibrary.wiley.com/doi/book/10.1002/9781119716846Copies:
Available:*
Library | Material Type | Item Barcode | Shelf Number | Status | Item Holds |
|---|---|---|---|---|---|
Searching... | E-Book | 598996-1001 | QD502.5 .M65 2024 | Searching... | Searching... |