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Conjugated polymer nanostructures for energy conversion and storage applications

Ghosh, Srabanti.

Conjugated polymer nanostructures for energy conversion and storage applications

Ghosh, Srabanti.

9783527820115

9783527820108

1 online resource (531 pages)

4.6 The Electrical and Physical Properties of Radiosynthesized CPs.

Cover -- Title Page -- Copyright -- Contents -- Preface -- Acknowledgment -- Part I Design and Characterization of Conjugated Polymer Nanostructures -- Chapter 1 Fundamentals of Conjugated Polymer Nanostructures -- 1.1 Introduction -- 1.2 Electronic and Electrical Properties -- 1.2.1 Conductive Mechanism -- 1.2.1.1 Inherent Molecular Structure -- 1.2.1.2 Doping and Band Structure Evolution -- 1.2.2 Charge Carrier Transport Models -- 1.2.3 Temperature Dependence -- 1.3 Electrochemical Properties -- 1.3.1 Reversible Oxidation/Reduction Process and Charge Storage Behavior

1.3.2 Swelling and De-swelling Behavior -- 1.3.3 Electrochromism -- 1.4 Optical Properties -- 1.4.1 Band Gap of Conjugated Polymers -- 1.4.2 Absorption and Emission -- 1.4.3 Coherent Exciton Diffusion and Energy Transfer -- 1.5 Unique Properties at the Nanoscale -- 1.6 Conclusion -- References -- Chapter 2 Chemical Synthesis of Conducting Polymers Nanostructures -- 2.1 Introduction -- 2.2 Template-Based Synthesis -- 2.2.1 Hard-Template Method -- 2.2.2 Soft-Template Method -- 2.3 Template-Free Synthesis -- 2.3.1 Self Assembly via Interfacial Polymerization

2.3.2 Post-synthetic Self-assembly Process -- 2.3.3 Wet Spinning Process -- 2.3.4 Melt Spinning -- 2.3.5 Dry Spinning -- 2.3.6 Electrospinning -- 2.3.7 Seeding Approach -- 2.3.8 Whisker Method of Polymer Synthesis -- 2.3.9 Mixed-Solvent Technique -- 2.3.10 Reprecipitation Technique -- 2.4 Conducting Polymer Hydrogels -- 2.5 Nanolithography -- 2.5.1 Dip-Pen Nanolithography (DPN) -- 2.5.2 Nanoimprint Lithography -- 2.6 Conclusion and Future Prospects -- References -- Chapter 3 Template-Free Synthesis of Nanostructured Conjugated Polymer Films -- 3.1 Introduction -- 3.2 Template-Free Synthesis

3.2.1 Electrochemical Polymerization -- 3.2.2 Electrospinning -- 3.2.3 Vapor Phase Polymerization -- 3.2.4 Plasma Polymerization -- 3.3 Conclusions -- References -- Chapter 4 Use of High Energy Radiation for Synthesis and Kinetic Study of Conjugated Polymers -- 4.1 Recent Advancements Toward Facile Preparation of Processable CPs -- 4.2 Preface to Radiation Induced Oxidative Polymerization of CPs Nanostructures in Aqueous Solutions -- 4.2.1 Studying Kinetic Mechanism of HO˙-Induced EDOT Polymerization in Aqueous Solution

4.2.2 Gamma-Radiation Induced Oxidative Polymerization of EDOT in Aerated Aqueous Solutions at Neutral pH -- 4.2.3 Effect of Oxidizing Species on Gamma-Radiation-Induced Synthesis of PEDOT -- 4.2.4 Extension of the Radiolytic Procedure to the Synthesis of Polypyrrole (PPy) Nanostructures -- 4.2.5 Effect of pH on the Polymerization of EDOT Monomers -- 4.3 Radiation-Induced Synthesis of CPs Nanostructures by Reduction-Polymerization Route -- 4.4 Radiation-Induced Synthesis of CPs/Metal Nanocomposites -- 4.5 Toward Radiation-Induced Synthesis of CPs Nanostructures in Organic Solvents

Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications is a comprehensive reference on conjugated polymers for energy applications. Distinguished academic and editor Srabanti Ghosh offers readers a broad overview of the synthesis, characterization, and energy-related applications of nanostructures based on conjugated polymers. The book includes novel approaches and presents an interdisciplinary perspective rooted in the interfacing of polymer and synthetic chemistry, materials science, organic chemistry, and analytical chemistry. This book provides complete descriptions of conjugated polymer nanostructures and polymer-based hybrid materials for energy conversion, water splitting, and the degradation of organic pollutants. Photovoltaics, solar cells, and energy storage devices such as supercapacitors, lithium ion battery electrodes, and their associated technologies are discussed, as well.

John Wiley and Sons

Nanostructured materials.

Energy storage.

Nanomatériaux.

Énergie -- Stockage.

Energy storage

Nanostructured materials

Ghosh, Srabanti.

https://onlinelibrary.wiley.com/doi/book/10.1002/9783527820115