Transition metal-catalyzed carbene transformations
tarafından
 
Wang, Jianbo, editor.

Başlık
Transition metal-catalyzed carbene transformations

Yazar
Wang, Jianbo, editor.

ISBN
9783527829170
 
9783527829156

Fiziksel Tanımlama
1 online resource.

İçerik
Alkane Functionalization by Metal-Catalyzed Carbene Insertion from Diazo Reagents / María Álvarez, Ana Caballero, Pedro J Pérez -- Catalytic Radical Approach for Selective Carbene Transfers via Cobalt(II)-Based Metalloradical Catalysis / Xiaoxu Wang, X Peter Zhang -- Catalytic Enantioselective Carbene Insertions into Heteroatom-Hydrogen Bonds / Ming-Yao Huang, Shou-Fei Zhu, Qi-Lin Zhou -- Engineering Enzymes for New-to-Nature Carbene Chemistry / Soumitra V Athavale, Kai Chen, Frances H Arnold -- Metal Carbene Cycloaddition Reactions / Kostiantyn O Marichev, Haifeng Zheng, Michael P Doyle -- Metal-Catalyzed Decarbenations by Retro-Cyclopropanation / Mauro Mato, Antonio M Echavarren -- Gold-Catalyzed Oxidation of Alkynes by N-Oxides or Sulfoxides / Kaylaa Gutman, Tianyou Li, Liming Zhang -- Transition-Metal-Catalyzed Carbene Transformations for Polymer Syntheses / Eiji Ihara, Hiroaki Shimomoto -- Metal-Catalyzed Quinoid Carbene (QC) Transfer Reactions / Hai-Xu Wang, Vanessa K-Y Lo, Chi-Ming Che -- Asymmetric Rearrangement and Insertion Reactions with Metal-Carbenoids Promoted by Chiral N,N-Dioxide or Guanidine-Based Catalysts / Xiaobin Lin, Xiaohua Liu, Xiaoming Feng -- Multi-Component Reaction via gem-Difunctionalization of Metal Carbene / Mengchu Zhang, Xinfang Xu, Wenhao Hu -- Transition-Metal-Catalyzed Cross-Coupling with Carbene Precursors / Kang Wang, Jianbo Wang.

Özet
Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.

Notlar
John Wiley and Sons

Konu Terimleri
Carbenes (Methylene compounds) -- Synthesis.
 
Metal catalysts.
 
Carbènes -- Synthèse.
 
Catalyseurs métalliques.
 
Organic.
 
Chemistry.
 
SCIENCE.
 
Metal catalysts

Yazar Ek Girişi
Wang, Jianbo,
 
Che, Chi-Ming,
 
Doyle, Michael P.,

Elektronik Erişim
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527829170


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