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Mixed-valence systems : fundamentals, synthesis, electron transfer, and applications

Zhong, Yuwu, editor.

Mixed-valence systems : fundamentals, synthesis, electron transfer, and applications

Zhong, Yuwu, editor.

9783527835287

1 online resource.

Front Matter -- Introduction and Fundamentals of Mixed-Valence Chemistry / Chun Y Liu, Miao Meng -- Conceptual Understanding of Mixed-Valence Compounds and Its Extension to General Stereoisomerism / Jeffrey R Reimers, Laura K McKemmish -- Quantum Chemical Approaches to Treat Mixed-Valence Systems Realistically for Delocalized and Localized Situations / Martin Kaupp -- Mixed Valency in Ligand-Bridged Diruthenium Complexes / Sanchaita Dey, Sudip Kumar Bera, Wolfgang Kaim, Goutam Kumar Lahiri -- Electronic Communication in Mixed-Valence (MV) Ethynyl, Butadiynediyl, and Polyynediyl Complexes of Iron, Ruthenium, and Other Late Transition Metals / Sheng Hua Liu, Ya-Ping Ou, František Hartl -- Electron Transfer in Mixed-Valence Ferrocenyl-Functionalized Five- and Six-Membered Heterocycles / Peter Frenzel, Heinrich Lang -- Electronic Coupling and Electron Transfer in Mixed-Valence Systems with Covalently Bonded Dimetal Units / Chun Y Liu, Nathan J Patmore, Miao Meng -- Mixed-Valence Electron Transfer of Cyanide-Bridged Multimetallic Systems / Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng -- Organic Mixed-Valence Systems: Toward Fundamental Understanding of Charge/Spin Transfer Materials / Akihiro Ito -- Mixed-Valence Complexes in Biological and Bio-mimic Systems / Xiangmei Kong, Yixin Guo, Zijie Zhou, Tianfei Liu -- Control of Electron Coupling and Electron Transfer Through Non-covalent Interactions in Mixed-Valence Systems / Zijie Zhou, Yixin Guo, Xiangmei Kong, Ying Wang, Tianfei Liu -- Stimulus-Responsive Mixed-Valence and Related Donor-Acceptor Systems / Jiang-Yang Shao, Yu-Wu Zhong -- Mixed Valency in Extended Materials / Harrison S Moore, Eleanor R Kearns, Martin P Koeverden, Deanna M D′Alessandro -- Near-Infrared Electrochromism Based on Intervalence Charge Transfer / Ying Han, Xiaohua Cheng, Yu-Wu Zhong, Bin-Bin Cui -- Manipulation of Metal-to-Metal Charge Transfer Toward Switchable Functions / Wen Wen, Yin-Shan Meng, Tao Liu -- Index

Mixed-Valence Systems Comprehensive overview on the advanced development of mixed-valence chemistry Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as: Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken-Hush theory, and analysis of the band shape of intervalence charge transfer Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.

John Wiley and Sons

Valence (Theoretical chemistry)

Valence (Chimie théorique)

Inorganic.

Chemistry.

SCIENCE.

Electronic books.

Zhong, Yuwu,

Liu, Chun Yuan,

Reimers, Jeffrey R.,

https://onlinelibrary.wiley.com/doi/book/10.1002/9783527835287