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Cover -- Series Page -- Title Page -- Copyright page -- Contents -- Preface -- Chapter 1 Green and Sustainable Catalytic Reaction Processes Including New Reaction Medium-Enriched Atom Utilization -- 1.1 Introduction -- 1.2 Background -- 1.2.1 Traditional Catalytic Reactions -- 1.2.2 Significance of Green and Sustainable Catalytic Reactions -- 1.2.3 New Reaction Medium-Enriched Atom Utilization -- 1.2.4 Overview of Research Problem -- 1.3 Literature Review -- 1.3.1 Sustainable Catalysis -- 1.3.2 Green Catalytic Processes -- 1.3.3 Atom Utilization in Catalysis -- 1.3.4 Reaction Medium for Green Catalysis -- 1.4 Environmental Impact of Catalytic Reactions -- 1.4.1 Impact of Traditional Catalytic Reactions -- 1.4.2 Environmental Benefits of Green Catalytic Reactions -- 1.4.3 Role of Reaction Medium in Reducing Environmental Impact -- 1.5 Experimental Section -- 1.5.1 Materials and Methodology -- 1.5.1.1 Materials -- 1.5.1.2 Methodology -- 1.5.2 Preparation of the Reaction Medium -- 1.5.3 Reaction Conditions -- 1.5.4 Analytical Techniques -- 1.6 Results and Discussion -- 1.6.1 Catalyst Characterization -- 1.6.2 Catalytic Activity and Efficiency -- 1.6.3 Atom Utilization Efficiency -- 1.6.4 Reaction Mechanism -- 1.6.5 Comparison with Traditional Catalytic Reactions -- 1.7 Summary and Outlook -- 1.7.1 Summary -- 1.7.2 Outlook -- References -- Chapter 2 Green Catalysis for Chemical Transformation: Need for the Sustainable Development -- 2.1 Introduction -- 2.2 Conclusion -- References -- Chapter 3 Green Avenues in Controlled Radical Polymerization for Precision Synthesis of Macromolecules -- 3.1 Introduction -- 3.2 Green Advances in Atom Transfer Radical Polymerization Technique -- 3.3 Green Advances in Reversible Addition Fragmentation Chain Transfer Polymerization Technique -- 3.4 Green Advances in Nitroxide-Mediated Polymerization Technique.

3.5 Conclusions and Future Perspective -- References -- Chapter 4 Catalytic Synthesis and Application of Heterocyclic and Heteroatom Compounds: Recent Advances -- 4.1 Introduction -- 4.1.1 Rhodium- and Silver-Catalyzed C-H Amidation -- 4.1.2 C-H Bond Activation/[4 + 2] Annulation Catalyzed by Rh(III) -- 4.1.3 Enantioselective Copper-Catalyzed Hydroalkylation -- 4.1.4 Multicomponent Copper-Catalyzed Synthesis of Quinoline Ring System -- 4.1.5 Iridium-Catalyzed Enantioselective Synthesis of Vabicaserin -- 4.1.6 Catalytic C-H Bond Functionalization -- 4.1.7 C-H Bond Activation of Heterocycles by Photoredox Pathway -- 4.1.8 Cu-Catalyzed Synthesis of Indole-Fused Oxazinone-1,2,3-Triazoles -- 4.1.9 3-Isothiocyanato Oxindoles as Substrates for Catalytic Asymmetric Synthesis of Spiroindoles -- 4.1.10 Palladium-Catalyzed Synthesis of Chiral Fused Spirooxindoles -- 4.1.11 Co(III)-Catalyzed Synthesis of 2,3-Disubstituted N-Alkyl Indoles -- 4.1.12 Co(III)-Catalyzed Synthesis of 2-Indolyl Propenols via C-H Bond Functionalization -- 4.2 Conclusion -- References -- Chapter 5 The Novel Trends in Asymmetric Catalysis: Green and Sustainable Catalysts -- 5.1 Introduction -- 5.1.1 Correlation Between Enzymatic Catalysis and the Green Chemistry Principle -- 5.2 Role of Green Synthesis and Catalyst -- 5.3 Asymmetric Hydrogenation Catalyzed by Transition Metals -- 5.3.1 The Asymmetric Hydrogenations are Caused by Cobalt -- 5.4 Asymmetric Cross-Couplings Catalyzed by TM -- 5.4.1 Asymmetrical Cross-Couplings for Profen Derivative Products Under Pd Catalysis -- 5.4.2 Asymmetrical Cross-Couplings for Profen Derivative Products Under Fe Catalysis -- 5.4.3 Asymmetrical Cross-Couplings for Profen Derivative Products Under Co-Catalysis -- 5.4.4 Asymmetrical Cross-Couplings for Profen Derivative Products Under Ni Catalysis.

5.4.5 Asymmetrical Cross-Couplings for Profen Derivative Products Under Cu-Catalysis -- 5.5 Approaches to Profens Through Organocatalysis -- 5.6 Conclusions -- Acknowledgments -- References -- Chapter 6 Application of Nanocatalysts in Greener Synthesis of Chemical Compounds -- 6.1 Introduction -- 6.2 Green Strategies -- 6.2.1 Synthesis of Green Nanocatalysts -- 6.2.2 Greener Reaction Condition -- 6.3 Nanocatalysts for Green Synthesis of Organic Compounds -- 6.4 Conclusion -- References -- Chapter 7 Heterogeneous Photocatalysis: Recent Advances and Applications -- 7.1 Introduction -- 7.2 Fundamental Principles of Photocatalysis -- 7.2.1 Bandgap Engineering -- 7.2.2 Charge Carrier Generation and Separation -- 7.2.3 Role of Photocatalytic Materials -- 7.3 Photocatalytic Mechanisms -- 7.3.1 Light Absorption and Electron-Hole Pair Generation -- 7.3.2 Charge Carrier Separation and Redox Reactions on the Photocatalyst Surface -- 7.3.3 Reactive Oxygen Species Generation -- 7.3.4 Langmuir-Hinshelwood and Surface Defect Engineering Mechanism -- 7.4 Factors Affecting Photocatalytic Efficiency -- 7.5 Recent Advances in Heterogeneous Photocatalysts -- 7.5.1 Metal-Organic Frameworks -- 7.5.2 Perovskites -- 7.5.3 Plasmonic Photocatalysts -- 7.6 Applications of Heterogeneous Photocatalysis -- 7.6.1 Water Splitting -- 7.6.2 CO2 Reduction -- 7.6.3 Pollutant Degradation -- 7.6.4 Organic Synthesis -- 7.7 Recent Advances in Enhancing Photocatalytic Performance -- 7.7.1 Cocatalyst Engineering for Charge Carrier Management -- 7.7.2 In Situ Photocatalyst Modification and Activation -- 7.7.3 Surface Defect Engineering and Co-Doping -- 7.7.4 Advanced Characterization Techniques in Photocatalysis -- 7.8 Prospects and Pioneering Challenges in Heterogeneous Photocatalysis -- 7.8.1 Future Directions -- 7.8.2 Challenges -- 7.9 Conclusion -- References.

Chapter 8 Role of Biocatalysis-Biotransformations in Sustainable Chemistry -- 8.1 Introduction -- 8.2 Principle of Biocatalysis -- 8.3 Recent Development in Biocatalysis -- 8.4 Future in Biocatalysis -- 8.5 Conclusion -- Acknowledgments -- References -- Chapter 9 Synthesis and Functionalization of Natural Products with Light-Driven Reactions -- 9.1 Introduction -- 9.2 Visible Light-Driven Total Synthesis of Natural Products -- 9.2.1 Total Synthesis of (-)-Actinophyllic Acid -- 9.2.2 Total Synthesis of (±)-Aglacin B/C -- 9.2.3 Total Synthesis of (1R, 3S)-Albucidin -- 9.2.4 Total Synthesis of (-)-Aspergillide A -- 9.2.5 Total Synthesis of (-)-Batrachotoxin -- 9.2.6 Total Synthesis of (-)-Burshernin -- 9.2.7 Total Synthesis of (±)-Cannabiorcicyclolic Acid -- 9.2.8 Total Synthesis of (+)-Cephalosporolides E and F -- 9.2.9 Total Synthesis of (±)-Cermizine -- 9.2.10 Total Synthesis of (-)-Chromodorolide B -- 9.2.11 Total Synthesis of (-)-Coerulescine -- 9.2.12 Total Synthesis of (±)-Crispine A -- 9.2.13 Total Synthesis of (±)-Danshenspiroketallactones -- 9.2.14 Total Synthesis of Daurioxoisoporphine C -- 9.2.15 Total Synthesis of Drimentine F -- 9.2.16 Total Synthesis of (±)-Epiraikovenal -- 9.2.17 Total Synthesis of (+)-Flavisiamine F -- 9.2.18 Total Synthesis of (-)-Flustraminol -- 9.2.19 Total Synthesis of (+)-GB22 -- 9.2.20 Total Synthesis of (+)-Gliocladin C -- 9.2.21 Total Synthesis of Hamigeran B -- 9.2.22 Total Synthesis of (±)-Heitziamide A -- 9.2.23 Total Synthesis of (±)-Hongoquercin A -- 9.2.24 Total Synthesis of Indotertine A -- 9.2.25 Total Synthesis of (-)-Kadsulignan E -- 9.2.26 Total Synthesis of (±)-Leptosperol B -- 9.2.27 Total Synthesis of (-)-Macfarlarndin C -- 9.2.28 Total Synthesis of (+)-Monomorine I -- 9.2.29 Total Synthesis of (±)-Norruspoline -- 9.2.30 Total Synthesis of (±)-Oxycodone -- 9.2.31 Total Synthesis of (-)-Pavidolide B.

9.2.32 Total Synthesis of (±)-Pellucidin A -- 9.2.33 Total Synthesis of Pentachloropseudilin -- 9.2.34 Total Synthesis of (-)-Polyoxamic Acid -- 9.2.35 Total Synthesis of (±)-Protolichesterinic Acid -- 9.2.36 Total Synthesis of (-)-Pseudotabersonine -- 9.2.37 Total Synthesis of (±)-Sceptrin -- 9.2.38 Total Synthesis of Tjipanazoles B and D -- 9.2.39 Total Synthesis of (±)-Tylophorine -- 9.2.40 Total Synthesis of (-)-Vincorine -- 9.2.41 Total Synthesis of (+)-Zephycarinatine D -- 9.3 Visible Light-Driven Functionalization of Natural Products -- 9.3.1 Functionalization of Aminoestrone -- 9.3.2 Functionalization of Caffeine -- 9.3.3 Functionalization of Cedrol -- 9.3.4 Functionalization of Methylvanillin -- 9.3.5 Functionalization of Steviol to (-)-Isoatisiane (247) -- 9.3.6 Functionalization of Tocopherol -- 9.3.7 Functionalization of Tyropotophan -- 9.4 Conclusion -- Acknowledgements -- References -- Chapter 10 Metrics of Green Chemistry and Sustainability -- 10.1 Green Metrics -- 10.1.1 Mass-Based Metrics -- 10.1.1.1 Percentage Yield -- 10.1.1.2 Atom Economy -- 10.1.1.3 Environmental Factor -- 10.1.1.4 Effective Mass Yield -- 10.1.1.5 Reaction Mass Efficiency -- 10.1.1.6 Mass Intensity and Process Mass Intensity -- 10.1.1.7 Mass Productivity -- 10.1.1.8 Carbon Efficiency -- 10.1.2 Impact-Based Metrics -- 10.1.2.1 The Eco-Scale -- 10.1.2.2 Toxicological Hazard Metrics -- 10.1.2.3 Global Hazard Metrics -- 10.1.2.4 Eco-Footprint -- 10.1.2.5 Summary of Impact-Based Metrics -- 10.2 Tools and Applications of Green Metrics -- 10.2.1 Green Metrics Applied in Analytical Chemistry -- 10.2.1.1 National Environmental Methods Index -- 10.2.1.2 Green Analytical Procedure Index -- 10.2.1.3 Analytical GREEnness -- 10.2.1.4 Analytical Eco-Scale -- 10.2.2 Green Metrics in Pharmaceutical Development -- 10.2.2.1 Green Solvent Selection Tool.

This groundbreaking book offers an in-depth description of sustainable green catalytic processes that have emerged as the means to empower the existing protocols with greener, sustainable, and environmentally benign versions that hold enormous potential in industry and society. Growing worldwide concerns about environmental pollution and global warming have directed the attention of scientists towards approaches for developing sustainable protocols, and the need for employing greener and more sustainable catalytic approaches that are environmentally greener and more eco-friendly than current ones. Green and sustainable catalysts are the one class of catalysts that possess higher selectivity and activity, efficient recovery from the reaction medium, recyclability, cost-effectiveness and are prepared using environmentally benign preparation techniques. The most potent instrument in organic synthesis, and the cornerstone of green chemistry, is catalysis which has broadened the possibilities for organic transformations in the direction of a sustainable future. The catalyst has been playing a vital role, from the improvement of reaction conditions to enhanced selectivity towards the intended product and a decrease in the creation of byproducts. The purpose of this book is to highlight the developments made towards designing new catalysts (homogeneous, heterogeneous, organocatalyst, nanocatalyst, photocatalyst, nanophotocatalyst, biocatalyst, nanobiocatalyst, metal catalyst etc,.) and present the advancements in the field of chemical synthesis using greener catalytic routes with far-reaching applications. The other environmentally friendly method is the enzymatic synthesis of organic molecules, which substitutes safe reagents for those that imitate the biosynthetic route to synthesize the desired organic molecules. With its ability to produce transformations that occasionally enable the reduction of steps in a synthetic route, biophotocatalysis has long been recognized as a green technology and key to creating environmentally friendly and sustainable chemistry. The employment of sustainable green processes on the most crucial reaction steps of the synthetic protocol satisfies contemporary needs for environmentally friendly operations during the creation of valuable chemicals. Readers will find the book: details new catalysts development designs (homo and heterogeneous); presents the advancement of organic synthesis using greener catalytic routes with far-reaching applications; elaborates on preparation techniques for green and sustainable catalysts that possess higher activity, efficient recovery, and cost-effectiveness; discusses how to epitomize a green approach towards the preparation of organic moieties via enzymatic synthesis; analyzes nano-catalysis with green-based reagents and solvents that allow producers to follow the fundamental pillars of the green economy; elucidates green chemistry's principles and metrics of the chemical's life cycle and design through disposal. Audience The core audiences for this book include scientists and engineers working in green chemistry, materials science, photocatalysts, biotechnology, nanotechnology, waste minimization, and sustainability. This book is an excellent resource for graduate students, R&D experts, and researchers in academic and industrial fields of chemical synthesis.

Kütüphane	Materyal Türü	Demirbaş Numarası	Yer Numarası	[[missing key: search.ChildField.HOLDING]]	Durumu/İade Tarihi
Çevrimiçi Kütüphane	E-Kitap	599401-1001	TP156 .C35 S87 2024		Wiley E-Kitap Koleksiyonu