Chiral building blocks in asymmetric synthesis : synthesis and application

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Başlık:

Yazar:

Wojaczyńska, Elżbieta, editor.

ISBN:

9783527834204

9783527834198

Fiziksel Tanımlama:

1 online resource.

Genel Not:

Includes index.

İçerik:

Front Matter -- Enantioselective Synthesis of Cyclopropenes / Virginie Carreras, Thierry Ollevier -- Chiral Heterocycles for Asymmetric Synthesis / Radovan Šebesta, Tibor Peňaška -- Saturated Heterocycles as Chiral Auxiliaries / Agnieszka Październiok-Holewa, Sebastian Stecko -- trans - 1,2-Diaminocyclohexane and Its Derivatives in Asymmetric Organocatalysis / Michał Kopyt, Michał P Głowacki, Piotr Kwiatkowski -- Diketopiperazines as Chiral Building Blocks / Juan Domingo Sánchez, Juan Francisco González, José Carlos Menéndez -- Amino Acids as Chiral Building Blocks / Elisabete P Carreiro, Anthony J Burke -- Carbohydrate-Based Catalysts and Auxiliaries in Organic Synthesis / Sebastian Baś, Szymon Buda, Jacek Młynarski -- Monoterpenes as Chiral Building Blocks / Agata J Pacuła-Miszewska, Magdalena Obieziurska-Fabisiak, Jacek Ścianowski -- Diterpene Acids as Starting Materials for the Synthesis of Biologically Active Compounds / Ignacio E Tobal, Alejandro M Roncero, Rosalina F Moro, David Díez, Isidro S Marcos -- Alkaloids as Chiral Building Blocks, Auxiliaries, Ligands, and Molecular Diversity / Karol Kacprzak, Elżbieta Wojaczyńska, Andrzej Trochimczuk, Franz Steppeler, Jacek Wojaczyński -- Chiral Building Blocks for Total Steroid Synthesis and the Use of Steroids as Chiral Building Blocks in Organic Synthesis / Izabella Jastrzębska, Douglas F Covey -- Chiral Organophosphorus Compounds in Asymmetric Synthesis / Elżbieta Łastawiecka, Sylwia Sowa, Katarzyna Szwaczko, Kamil Dziuba, Marek Stankevič, Adam Włodarczyk -- Organosulfur Compounds as Chiral Building Blocks / Maria AM Capozzi, Cosimo Cardellicchio -- Organoselenium Compounds as Chiral Building Blocks / Luana Bagnoli, Claudio Santi -- Allenes as Chiral Building Blocks in Asymmetric Synthesis / Rafał Loska, Alicja Wasilewska-Rosa -- The Synthesis and Application of BINOL Derivatives as Effective Building Blocks for Catalysts Employed in Enantioselective Synthesis / Janusz Jurczak, Patryk Niedbała, Agata Tyszka-Gumkowska -- Chiral Acenes: Synthesis and Applications / Andrea Nitti, Giovanni Preda, Dario Pasini -- 2-Aza-21-Carbaporphyrin in Construction of Chiral Supramolecular Assemblies / Sebastian Koniarz, Piotr J Chmielewski -- Catenane, Rotaxane, and Molecular Knot Chiral Building Blocks / Jean-Claude Chambron -- Index

Özet:

Chiral Building Blocks in Asymmetric Synthesis A comprehensive introduction to the important classes of chiral building blocks Chirality -- the asymmetric quality found in certain chemical compounds -- plays an essential role in our world: chiral compounds can be found in biology, pharmaceutical compounds, agrochemicals, and fragrances. The stereoselective preparation of these complex molecular constructions constitutes a challenge. To this end, modern asymmetric synthesis utilizes a variety of valuable and efficient reagents employed as chiral auxiliaries, metal complexes and organocatalysts in stereoselective catalysis, and enantiopure reactants termed as chiral building blocks. In Chiral Building Blocks in Asymmetric Synthesis, the achievements in the fields of preparation of and applications of chiral blocks are presented. In doing so, the book comprehensively discusses the important classes of these reactants as the key for the asymmetric synthesis of chiral molecules. As such, it is an indispensable resource about synthetic methods, as well as possible modifications and transformations of important classes of chiral compounds. It also highlights the importance of their use as reactants and auxiliaries in the preparation of more sophisticated molecules or supramolecular systems. In Chiral Building Blocks in Asymmetric Synthesis readers will also find: Organization according to the most important compound classes -- e.g. amino acids, BINOL and its derivatives, terpenes, and others -- with an emphasis on synthesis and application A focus on the use of chiral building blocks for the preparation of bioactive compounds and supramolecular assemblies Chiral Building Blocks in Asymmetric Synthesis is a useful reference for organic chemists, catalytic chemists, chemists in industry, medicinal chemists, pharmaceutical chemists, and the libraries that support them.

Notlar:

John Wiley and Sons

Konu Terimleri:

Chirality.

Asymmetric synthesis.

Chiralité.

Synthèse asymétrique.

Physical & Theoretical.

Industrial & Technical.

Chemistry.

SCIENCE.

Materials Science.