
Başlık:
Donor-acceptor cyclopropanes in organic synthesis
Yazar:
Banerjee, Prabal, editor.
ISBN:
9783527835652
9783527835645
Fiziksel Tanımlama:
1 online resource (464 pages)
İçerik:
Preface 1) Introduction to the Chemistry of Donor-Acceptor Cyclopropanes: A Historical and Personal Perspective 2) Understanding Reactivity of Donor-Acceptor Cyclopropanes: Structural and Electronic Analysis 3) Cycloaddition and Annulation Reactions of Donor-Acceptor Cyclopropanes 4) Activation of Donor-Acceptor Cyclopropanes under Covalent Organocatalysis: Enamine, Iminium, NHC and Phosphine Catalysis 5) Ring-Opening 1,3-Difunctionalization of Donor-Acceptor Cyclopropanes 6) Molecular Rearrangements in Donor-Acceptor Cyclopropanes 7) Donor-Acceptor Cyclopropanes with Amino Group as Donor 8) Chemistry of Cyclopropyl Monocarbonyls 9) Chemistry of Aroyl- and Nitro-substituted Donor-Acceptor Cyclopropanes 10) Metal-free Activation of the Donor-Acceptor Cyclopropanes: Thermal Reactions, Protic Acids and Bases 11) Asymmetric Catalytic Activation of Donor-Acceptor Cyclopropanes 12) Donor-Acceptor Cyclopropanes in Natural Product Synthesis
Özet:
Donor-Acceptor Cyclopropanes in Organic Synthesis Facilitate milder, simpler reactions in organic synthesis with this cutting-edge family of building blocks Donor-Accepted Cyclopropanes, or DACs, have attracted a resurgence of interest from organic chemists in recent decades for their role in facilitating various reactions such as cycloadditions, annulations, ring-opening and enantioselective transformations. The structural arrangement of DACs leads to milder, simpler reaction conditions, which have made them indispensable for a range of fundamentally and industrially important processes. Donor-Acceptor Cyclopropanes in Organic Synthesis covers comprehensively the chemistry and applications of this compound class. The result is an invaluable guide for any researcher looking to bring DACs to bear in their own areas of research or development. Readers will also find: A brief introduction of the history and reactivity of DACs Detailed discussion of reactions including Lewis acid-catalyzed cycloadditions, metal-free activation, asymmetric transformations, organocatalysis, and many more Application of DACs in natural product synthesis and pharmaceutical/agrochemical research Donor-Acceptor Cyclopropanes in Organic Synthesis is ideal for organic chemists, experts in catalysis, pharmaceutical researchers, and any other scientists interested in facilitating milder, simpler reactions.
Notlar:
John Wiley and Sons
Tür:
Elektronik Erişim:
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527835652Kopya:
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Kütüphane | Materyal Türü | Demirbaş Numarası | Yer Numarası | Durumu/İade Tarihi | Materyal Ayırtma |
|---|---|---|---|---|---|
Arıyor... | E-Kitap | 598983-1001 | QD305 .H9 | Arıyor... | Arıyor... |
