This book constitutes the refereed proceedings of the 14th International Conference on Advances in Optimization and Applications, OPTIMA 2023, held in Petrovac, Montenegro, during September 18-22, 2023. The 21 full papers included in this book were carefully reviewed and selected from 68 submissions. They were organized in topical sections as follows: mathematical programming; global optimization; continuous optimization; discrete and combinatorial optimization; optimal control; game theory and mathematical economics; optimization in economics and finance; and applications.